Articulated rods – a novel class of molecular rods based on oligospiroketals (OSK)
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چکیده
منابع مشابه
Articulated rods – a novel class of molecular rods based on oligospiroketals (OSK)
We developed a new type of molecular rods consisting of two (or more) rigid units linked by a flexible joint. Consequently we called these constructs articulated rods (ARs). The syntheses of ARs were carried out by a flexible and modular approach providing access to a number of compounds with various functionalizations in terminal positions. First applications were presented with pyrene, cinnam...
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Fully conjugated pyrene-anthracene-based molecular rods were synthesized by the Horner-Wadsworth– Emmons reaction utilizing potassium tert-butoxide in dry THF. The synthesized rods, which have butylene groups as solubility spacers in the main chain, exhibited good solubility in polar solvents. The solutions of the synthesized pyrenecontaining molecular rods exhibited a blue shift in the UV-vis ...
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ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2015
ISSN: 1860-5397
DOI: 10.3762/bjoc.11.11